🔬 Understanding the Thermal Decomposition of Lithium Hydroxide Monohydrate (LiOH·H₂O)

As demand for battery and new energy materials continues to grow, controlling the thermal behavior of lithium compounds becomes increasingly critical.

Lithium hydroxide monohydrate plays a key role in cathode material production, and its dehydration and decomposition directly affect:

✔ Sintering temperature design
✔ Lithium stoichiometry control
✔ Material purity
✔ Process stability

Based on STA analysis under oxygen atmosphere (25–800°C, 5°C/min), the transformation pathway can be summarized as:

📌 31.8–130.3°C – Dehydration (~11.31% weight loss)
📌 198.9–456.4°C – Critical decomposition zone (~12.53% weight loss)
📌 >600°C – Li₂O enters a relatively stable region

Precise temperature control in the 200–450°C range is especially important to prevent lithium loss and composition deviation during cathode material processing.


At CeramXpert, we supply laboratory consumables and advanced ceramic components used in materials analysis, thermal analysis, and general lab testing.

Our main product categories include:

🔹 Thermal analysis consumables — crucibles, sample pans, lids, sealing tools, etc.
(Compatible with Mettler Toledo, Netzsch, PerkinElmer, TA, Hitachi/Seiko, Leco, and more.)

🔹 Advanced ceramics — alumina, zirconia, boron nitride, aluminum nitride, quartz — designed for high-temperature and chemically demanding environments.

Our products are widely used by:

• Materials R&D laboratories
• Universities and research institutes
• Polymer & battery manufacturers
• Metallurgy, ceramics, and chemical labs
• QA/QC testing facilities

If you are working with lithium compounds or thermal analysis applications, we’re happy to support your lab with reliable and cost-effective solutions.

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